Pub. Date:
Basic Books
Oxygen Complexes and Oxygen Activation by Transition Metals

Oxygen Complexes and Oxygen Activation by Transition Metals

by Arthur E. Martell, Donald T. Sawyer


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Product Details

ISBN-13: 9780306427893
Publisher: Basic Books
Publication date: 10/28/1988
Pages: 341
Product dimensions: 6.50(w) x 1.50(h) x 9.50(d)

Table of Contents

Opening Remarks.- Dioxygen Complexes with Transition Metals.- Bonding of Dioxygen to Transition Metals.- Oxygen Binding by the Metalloproteins Hemerythrin, Hemocyanin, and Hemoglobin.- Metal Oxo Complexes and Oxygen Activation.- Kinetics of Formation of Biological Oxygen Carriers.- Synthetic Dioxygen Carriers for Dioxygen Transport.- Formation and Degradation of Cobalt Dioxygen Complexes.- Reversible Complexes for the Recovery of Dioxygen.- Summary - Dioxygen Complexes with Transition Metals.- Oxygen Activation by Transition Metals.- Summary - Oxygen Activation by Transition Metals.- The Chemistry and Activation of Dioxygen Species (02, 02-., and H00H) in Biology.- Oxygen Activation by Neutrophils.- Mechanisms of Dioxygen Activation in Metal-Containing Monooxygenases: Enzymes and Model Systems.- Radical Cation Pathways for Selective Catalytic Oxidation by Molecular Oxygen.- Vanadium Catalyzed Autoxidation of Hydrogen Sulfide.- Copper Catalyzed Oxidative Carbonylation of Methanol to Dimethyl Carbonate.- Dependence of Reaction Pathways and Product Distribution on the Oxidation State of Palladium Catalysts for the Reactions of Olefinic and Aromatic Substrates with Molecular Oxygen.- Oxygen Activation and Oxidation Reactions on Metal Surfaces.- Methane Oxidation at Metal Oxide Surfaces.- The Activation of Oxygen by Metal Phosphorus Oxides - The Vanadium Phosphorus Oxide Catalyst.- The Oxidation of Organic Compounds by Metal Complexes in Zeolites.- Abstracts of Posters.- Kinetics and Mechanisms of Degradation of Binuclear Cobalt Dioxygen Complexes.- Methane Activation over Lanthanide Oxides.- Dioxygen Affinities of Some Synthetic Cobalt Schiff Base Complexes.- Temporal Analysis of Products (TAP): A Unique Catalyst Evaluation System with Sub-Millisecond Time Resolution.- Dioxygen Insertion into Metal-Carbon Bonds of Metalloporphyrins: Formation and Characterization of Alkylperoxy Metalloporphyrins.- Iron Porphyrin Catalyzed Air Oxidation of Aldehydes and Alkenes.- Oxidative Dimerization of Methane over Sodium-Promoted Calcium Oxides.- Synthesis and Metal Ion Affinities of a Binucleating Polyamine: Reversible Formation of a Cobalt Dioxygen Complex.- Potentiometric Determination of Stabilities of Cobalt(II) Complexes of Polyamine Schiff Bases and Their Dioxygen Adducts.- Catalysis of Cobalt Schiff Base Complexes for the Oxygenation of Olefins. Mechanisms for the Ketonization Reaction.- Selective Oxidation of Saturated Hydrocarbons by the Gif and Gif-Orsay Systems.- The Formation, Characterization, and Reactivity of the Oxene Adduct of Tetrakis(2,6-dichlorophenyl)porphinato-Iron(III) Perchlorate in Acetonitrile.- Preparation and Characterization of a Binuclear Iron(III)- Hydroxo-y-hydroperoxy Complex [(Ph3PO)4(HO)FeIII(HOOH)FeIII(OH)(OPPh3)4](C1O4)4.- Autoxidation of FeII(dihydroxyphenanthroline)3.- Phosphine-Ruthenium(II)-Aquo Redox Chemistry: The Aerobic Catalytic Oxidation of Cyclohexene.- The Oxidation of Organic Substrates by Molecular Oxygen; Catalysis by Ru(III) and Ru(III)-EDTA.- Oxygenation of Tryptophane Catalyzed by Polyamine Cobalt Dioxygen Complexes.- Resonance Raman Spectroscopy of the Fe(IV)=0 Group in Peroxidase Intermediates.- Reaction of Dioxygen with Synthetic Copper(I) Compounds of Biological Relevance.- Thorough Elucidation of Oxygenation- and Oxidation-Mechanisms of Iron(II) Porphyrin on the Basis of a New Hypothesis for an Electron-Transfer Pathway.- IUCCP Description.

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